Ignition Delay of Biodiesel and Biodiesel Surrogate Fuel Droplets

Principal Investigator:

Anthony J. Marchese, Ph.D.
Associate Professor
Department of Mechanical Engineering
College of Engineering
Rowan University
201 Mullica Hill Road
Glassboro, NJ 08028-1701
Email: marchese@rowan.edu
Telephone: (856) 256-5343

Project Summary

Biodiesel has been shown to be highly effective in reducing CO, HC, PM and greenhouse gas emissions from diesel engines, decreasing dependence on petroleum imports and developing new markets for domestic agricultural products such as soybeans. Unfortunately, most studies have also shown that biodiesel results in an increase in NOx emissions. The complete mechanism behind the NOx increase from biodiesel is not completely understood but evidence suggests that it is caused by differences in both the physical properties and the chemical oxidation mechanisms between biodiesel and petroleum diesel. To date, the contribution to the biodiesel NOx increases related to differences in chemical kinetics has received very little attention. Similarly, the chemical kinetic mechanism responsible for the dramatic decreases in PM emissions from biodiesel is also poorly understood. As a first step in understanding the chemical kinetic mechanisms behind biodiesel NOx and PM processes, appropriate surrogate fuels must be identified that have similar chemical structure (and/or autoignition characteristics) to the long chain methyl esters found in biodiesel.

In this research, droplet ignition delay experiments are conducted using a variety of methyl esters and the results are compared to commercial soy methyl ester biodiesel. Specifically, fuel droplets were injected into a tube furnace containing atmospheric air at temperatures up to 1000 C. The ignition event is characterized by measurement of UV emission from hydroxyl radical (OH*) chemiluminescence.   n addition to the biodiesel surrogate fuels, experiments are conducted using methanol, for which a validated, detailed kinetic mechanism exists. The experimental results for methanol are compared against a detailed, time-dependent numerical model.  Droplet ignition experiments are chosen as a means to evaluate liquid biodiesel surrogate fuels because spherically symmetric droplet combustion represents the simplest two-phase, time-dependent chemically reacting flow system that can be solved numerically with detailed chemical kinetics and transport.  To obtain spherical symmetry, experiments are conducted using the 1.1-second drop tower at Rowan University.

Publications

• Gail, S., Thomson, M., Sarathy, S. M., Syed, S. A., Dagaut, P., Dievart, P., Marchese, A. J. and Dryer, F. L. (2006). A Wide Range Kinetic Modeling Study of Methyl Butanoate. Proc. Combust Inst. Accepted for Publication.
• Vaughn, T., Hammill, M., Harris, M., Wessel, M. and Marchese, A. J. (2006). Microgravity Ignition Delay of Bio-Ester Fuel Droplets. AIAA-2007-0741, 45h Annual Aerospace Sciences Meeting, Reno, NV, Jan. 2007. Submitted.
•  Vaughn, T., Hammill, M., Harris, M. and Marchese, A. J. (2006). Ignition Delay of Bio-Ester Fuel Drop-lets. SAE 2006-01-3302. SAE Powertrain & Fluid Systems Conference and Exhibition, Toronto, Canada, October 16-19, 2006. Accepted.
• Vaughn, T., Harris, M., Hammill, M., Wessell, M, and Marchese, A. J. (2006). Ignition Delay of Biodiesel Surrogate Fuels. Work-in-Progress Poster Session. Thirty First Symposium (International) on Combustion. Heidelberg, Germany, August 2006.
• Vaughn, T., Hammill, M., and Marchese, A. J. (2006). Ignition Delay of Biodiesel and Biodiesel Surrogate Fuel Droplets. Central States Meeting of the Combustion Institute, Cleveland, OH, May 2006.
• Hammill, M., Vaughn, T. and Marchese, A. J. (2005). Ignition Delay of Oxygenated Fuel Droplets.  Fall Technical Meeting of the Eastern States Section of the Combustion Institute, Orlando, FL, November 2005.

Project Personnel

Anthony Marchese, PI

Matt Hammill, '03,'05

Tim Vaughn, '05,'06

Mark Wessel, '06, '07

Michael Harris, '06

Last Updated: August 30, 2006